This phrase is mainly used in the UK and might not be well understood outside of it. After the project ended, I was glad to be shot of the extra work.
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Negative Context
Used when you're relieved to be free from something negative or burdensome. Once the exams were over, students were eager to get shot of their study notes.
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Informal Tone
The phrase is casual and might be too informal for professional or academic settings. I can't wait to get shot of this old laptop and buy a new one.