Used during leisure time among friends or acquaintances, not in professional situations. At the family BBQ, we often shoot the breeze about old times.
Pro Tip 2/3
No Agenda
Conversations are spontaneous without a specific topic or purpose. While fishing, they'd shoot the breeze, talking about everything and nothing.
Pro Tip 3/3
Casual Relationships
Often indicates a friendly relationship, but not necessarily a close one. Sometimes I shoot the breeze with neighbors I barely know, just to be polite.