Use it when highlighting the absence of something very important for survival or function. The village will starve of clean water if the drought continues.
Pro Tip 2/3
Metaphorical Use
Often used metaphorically to describe a dire need, not just physical starvation. Artists often feel they starve of inspiration in a monotonous environment.
Pro Tip 3/3
Emotional Emphasis
Conveys a strong emotional response associated with the urgent need for something. After months in isolation, he was starving of human contact.