Refers to someone responsible for the operations of a train station, not just any employee. The stationmaster is busy coordinating today's train schedules.
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Authority Figure
The word implies authority and leadership within the railway system. Speak to the stationmaster if you have any complaints about the service.
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Historical Context
Historically prestigious, the role was essential for railway communication and efficiency. In the past, the stationmaster would communicate train arrivals using telegraph.