Used more in fairy tales, fantasy, and mythology than in modern conversation. The enchantress in the forest bewitched all who dared enter.
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Gender Specific
Refers exclusively to women. Men with similar qualities might be called 'wizards' or 'sorcerers'. The old tales often speak of noble knights and cunning enchantresses.
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Historical Connotation
Historically, enchantresses were sometimes viewed suspiciously or as evil. The villagers feared the enchantress, believing she caused the illnesses.