'Gentlefolk' is old-fashioned and mainly found in historical or period contexts. In the novel, the gentlefolk attended the grand ball in elaborate attire.
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Cultural Nuance
'Gentlefolk' implies refinement often associated with the upper classes in past British society. The manor was known to be inhabited by gentlefolk of considerable wealth.
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Behavior Implied
Using 'gentlefolk' suggests polite, courteous behavior, not just social status. She behaved like gentlefolk should, never raising her voice in public.