Use 'peckish' when you're only a little hungry, not starving or very hungry. After the long meeting, I was feeling a bit peckish but could wait for dinner.
Pro Tip 2/3
Informal
'Peckish' is casual; it fits well in informal chats, not formal or academic writing. Wanna grab a bite? I’m kind of peckish right now.
Pro Tip 3/3
British Usage
'Peckish' is mostly used in British English, less so in American English. While in London, I noticed people commonly saying they were 'peckish' around tea time.