Use 'unwonted' to express an element of surprise due to rarity or unexpectedness in a situation or behavior. The unwonted cheerfulness of the usually solemn professor took everyone by surprise.
Pro Tip 2/3
Negative Context
'Unwonted' can be used to denote a negative deviation from someone's typical behavior or situation. His unwonted outburst of anger left us all in shock.
Pro Tip 3/3
Intensity Scale
When describing intensity, 'unwonted' suggests a level beyond what is normal, but not necessarily extreme. After the speech, she felt an unwonted sense of importance among her peers.