Chance on Definition 1 of 1Pro Tip 1/3Unplanned Discovery Use 'chance on' when describing a surprising discovery made without a plan or expectation. While hiking, we chanced on a secluded waterfall. Pro Tip 2/3Casual Encounters 'Chance on' often implies a casual or unexpected encounter with a person or thing. In the library, I chanced on my professor. Pro Tip 3/3Serendipitous Tone The phrase conveys a positive tone, suggesting a fortunate or happy accident. She chanced on a rare first edition at the flea market.