Used when someone acts in a way that's surprisingly different from usual behavior or expectations. Normally a team player, he went rogue and made a decision without consulting anyone.
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Colloquial Usage
It's often used in casual conversation rather than in formal writing. After years of following orders, she went rogue and started her own business.
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Negative Connotation
Can imply disobedience or breaking rules, sometimes viewed negatively. The agent went rogue, disregarding the agency's protocol.