Use it when revealing information that is unexpected or adds impact. She's fluent in three languages, not to mention she's also a skilled violinist.
Pro Tip 2/3
Additional Emphasis
It emphasizes an extra point that strengthens or supports what you've just said. The car is fast and stylish, not to mention it’s extremely fuel-efficient.
Pro Tip 3/3
Somewhat Informal
It's casual, suitable for conversational context, rather than formal writing. He's got experience, not to mention a great sense of humor.