Use 'parvenu' for someone new to wealth or status but seen as trying too hard to fit in. The old elites saw him as a parvenu who tried to mimic them without grace.
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Negative Tone
'Parvenu' often carries a negative judgement about someone's social abilities. She was labeled a parvenu for her ostentatious display of wealth.
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Cultural Context
Understanding historical class systems will help with the connotations of 'parvenu'. In Victorian novels, a parvenu was often shunned by the aristocracy.